Four terminal perovskite-silicon PV tandem devices hit 30% efficiency

The result is presented during the 8^th World Conference on Photovoltaic Energy Conversion (WCPEC-8) in Milan and has been achieved by combining the emerging perovskite solar cell with conventional silicon solar cell technologies. The perovskite cell that features transparent contacts and is part of the tandem stack has been independently certified.

Additionally, achieving high-power density will create more opportunities to integrate these solar cells into construction and building elements, so that more existing surface area can be covered with PV modules. Breaking the 30% barrier is therefore a big step in accelerating the energy transition and improving energy security by reducing the dependency on fossil fuels.

The best of both worlds

Tandem devices can reach higher efficiencies than single junction solar cells because of a better utilization of the solar spectrum. The currently emerging tandems combine commercial silicon technology for the bottom device with perovskite technology: the latter featuring highly efficient conversion of ultraviolet and visible light and excellent transparency to near infrared light.

In four-terminal (4T) tandem devices the top and bottom cells operate independently of each other which makes it possible to apply different bottom cells in this kind of devices. Commercial PERC technology as well as premium technologies like heterojunction or TOPCon or thin-film technology such as CIGS can be implemented in a 4T tandem device with hardly any modifications to the solar cells. Furthermore, the four-terminal architecture makes it straight forward to implement bifacial tandems to further boost the energy yield.

Researchers from the Netherlands and Belgium have successfully improved the efficiency of the semi-transparent perovskite cells up to 19.7% with an area of 3x3 mm² as certified by ESTI (Italy).

“This type of solar cell features a highly transparent back contact that allows over 93% of the near infrared light to reach the bottom device. This performance was achieved by optimizing all layers of the semi-transparent perovskite solar cells using advanced optical and electrical simulations as a guide for the experimental work in the lab.” says Dr Mehrdad Najafi of TNO. “The silicon device is a 20x20-mm² wide, heterojunction solar cell featuring optimized surface passivation, transparent conductive oxides and Cu-plated front contacts for state-of-the-art carrier extraction” says Yifeng Zhao PhD student at TU Delft, whose results have been recently peer-reviewed.

The silicon device optically stacked under the perovskite contributes with 10.4% efficiency points to the total solar energy conversion. Combined, 30.1% is the conversion efficiency of this non-area matched 4T tandem devices operating independently. This world’s best efficiency is measured according to generally accepted procedures.

Future of four terminal tandem PV modules

This is not all, combining this highly transparent perovskite cell with other silicon-based technologies such as back contact (metal wrap through and interdigitated back contact cells) and TOPCon solar cells has also delivered conversion efficiencies approaching 30%. This demonstrates the potential of highly transparent perovskite solar cells and their flexibility to be combined with already commercialized technologies. These world best efficiencies obtained on a multitude of incumbent technologies is a further milestone towards industrial deployment.

Acknowledgements:

• TNO (Netherlands Organization for Applied Scientific Research), Tandem PV Technology & Application program is supported by Research and Cooperation Fund (SMO) from the Netherlands Ministry of Economic Affairs and Climate Policy. TNO also acknowledges the collaboration with Forschungszentrum Jülich.
• Dutch Joint Solar Program III (JSPIII) is a cooperation of Delft University of Technology (TU Delft), Eindhoven University of Technology (TU/e), University of Amsterdam and research institute AMOLF. The aim of the JSPIII program is to gain fundamental knowledge and develop technologies required for achieving 30% efficiency tandem devices based on crystalline silicon and thin-film perovskite solar cells. The program is financed by Dutch NWO organization, TNO and industrial partners Shell, Tempress, Levitech, Exasun, and Eternal Sun.
• Hiper XL: This work received funding from RVO/TKI Urban Energy Programme (TKI toeslag) for research and innovation via the HIPER XL project (project number 1921202). This project is supported under the umbrella of SOLAR-ERA.NET Cofund by RVO (NL), Tubitak (TR), AEI (ES)]. SOLAR-ERA.NET is supported by the European Commission within the EU Framework Programme for Research and Innovation HORIZON 2020 (Cofund ERA-NET Action, N° 691664)